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General Chemistry
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Protein-Pd Complexes Conjugates as Artificial Enzymes
Jose M Palomo*,a and Esteban P. Urriolabeitia*,b
a Department of Biocatalysis, Institute of Catalysis (CSIC)Marie Curie 2. Cantoblanco. Campus UAM, 28049Madrid, Spain
b Instituto de Síntesis Quimica y Catálisis Homogénea (ISQCH, CSIC-Universidad de Zaragoza), C/Pedro Cerbuna 12, Zaragoza, E-50009, Spain
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Abstract  The combination of enzymes and palladium organometallic complexes has been recently developed for the creation of new types of artificial metalloenzymes. Different methods considering the kind of protein used, from a core protein to an enzyme, or the strategies for the selective insertion of the organometallic complex from direct Pd bonding to protein amino acid, affinity interactions or covalent attachment by a Pd complex ligand have been developed. This methodology affords new Pd catalysts with highest selectivity and activity in different reactions at milder conditions compared with the free Pd complexes.
Keywords metalloenzymes      palladium complexes      hybrids      organometallics     
Corresponding Authors: Email: (J. M. P.), (E. P. U.)   
Just Accepted Date: 02 December 2019   Online First Date: 03 December 2019   
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Jose M Palomo
Esteban P. Urriolabeitia
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Jose M Palomo,Esteban P. Urriolabeitia. Protein-Pd Complexes Conjugates as Artificial Enzymes[J]. General Chemistry, 03 December 2019. [Epub ahead of print] doi: 10.21127/yaoyigc20190030.
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