Please wait a minute...
 Home  Guidelines for Reviewers About the Journal News Editorial Board Aims & Scope Peer Review Policy Subscription Contact us Announcement
 
Early Edition  //  Current Issue  //  Archives  //  Most Read
General Chemistry
Perspective |
Protein-Pd Complexes Conjugates as Artificial Enzymes
Jose M Palomo*,a and Esteban P. Urriolabeitia*,b
a Department of Biocatalysis, Institute of Catalysis (CSIC)Marie Curie 2. Cantoblanco. Campus UAM, 28049Madrid, Spain
b Instituto de Síntesis Quimica y Catálisis Homogénea (ISQCH, CSIC-Universidad de Zaragoza), C/Pedro Cerbuna 12, Zaragoza, E-50009, Spain
Download: PDF(302 KB)  
Export: BibTeX | EndNote | Reference Manager | ProCite | RefWorks     Supporting Info
Abstract  The combination of enzymes and palladium organometallic complexes has been recently developed for the creation of new types of artificial metalloenzymes. Different methods considering the kind of protein used, from a core protein to an enzyme, or the strategies for the selective insertion of the organometallic complex from direct Pd bonding to protein amino acid, affinity interactions or covalent attachment by a Pd complex ligand have been developed. This methodology affords new Pd catalysts with highest selectivity and activity in different reactions at milder conditions compared with the free Pd complexes.
Keywords metalloenzymes      palladium complexes      hybrids      organometallics     
Fund: 
Corresponding Authors: Email: josempalomo@icp.csic.es (J. M. P.), esteban@unizar.es (E. P. U.)   
Just Accepted Date: 02 December 2019   Online First Date: 03 December 2019   
0
Service
E-mail this article
E-mail Alert
RSS
Articles by authors
Jose M Palomo
Esteban P. Urriolabeitia
Cite this article:   
Jose M Palomo,Esteban P. Urriolabeitia. Protein-Pd Complexes Conjugates as Artificial Enzymes[J]. General Chemistry, 03 December 2019. [Epub ahead of print] doi: 10.21127/yaoyigc20190030.
URL:  
http://www.genchemistry.org/EN/10.21127/yaoyigc20190030    
[1] Mengfan Wang, Qian Tao, Bo Liu, Chengchao Li, Libao Chen, Chenglin Yan. On-Chip, Mediator- and Membrane-Less Micro-Glucose Biofuel Cells Based on Layer-by-Layer Reduced Graphene Oxide-Enzyme Hybrids[J]. General Chemistry, 2018, 4(2): 180001-180001.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
沪ICP备15041762号-2
Copyright © General Chemistry, All Rights Reserved.
Address: 425 East 76th Street, Apt 9E, New York, NY, 10021, United States