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General Chemistry ›› 2018, Vol. 4 ›› Issue (4): 180019-.DOI: 10.21127/yaoyigc20180019

Special Issue: Fullerenes

• Minireviews • Previous Articles     Next Articles

Molecular Fullerenes Encapsulated in Metal-Organic Frameworks

Haibing Meng, 1, 2, Chunru Wang, 1, Taishan Wang1, *   

  1. 1 Beijing National Laboratory for Molecular Sciences, Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
    2 University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2018-07-10 Revised:2018-08-07 Online:2018-12-29 Published:2018-12-29
  • Supported by:
    This work was supported by the National Natural Science Foundation of China (Nos. 61227902, 51672281, 51472248) and the Beijing Natural Science Foundation (No. 2162050). T. Wang particularly thanks the Youth Innovation Promotion Association of CAS (No. 2015025).

Abstract: Fullerenes have many potential applications in various fields such as biomedicine, organic photovoltaics, molecular device, et al. However, it is still meaningful to explore more functional fullerene materials due to their special structures and attractive properties. In recent years, metal-organic frameworks (MOFs) have gained particular interest due to their potential applications in gas storage, catalysis, sensing, electronics, biomedicine, and so on. Considering the porous character of MOFs, it is fascinating to encapsulate molecular fullerenes into MOF pores and to construct new complex materials with unique properties and applications. In this minireview, we discuss the up-to-date study progress for the fullerene@MOF materials. We introduce firstly the preparation strategies, and then summarize the applications of these fullerene@MOF materials.

 

Key words: fullerenes, metal-organic frameworks, host-guest interaction, complex materials

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